Matches in SemOpenAlex for { <https://semopenalex.org/work/W2070291004> ?p ?o ?g. }
Showing items 1 to 65 of
65
with 100 items per page.
- W2070291004 endingPage "1776" @default.
- W2070291004 startingPage "1770" @default.
- W2070291004 abstract "Phenolyses of optically active 1-phenylethyl chloride were carried out in phenol (50°C), p-cresol (100°C), p-chlorophenol (100°C), and 2,6-xylenol (100°C in the presence of variable concentrations of the sodium salts of the respective phenols or triethylamine; the distributions (%) for the O- and C-alkylation products and the net steric courses (α%) for each product were examined. The distribution and the steric course which were graphically extrapolated to the zero base concentration indicated that, if the influence of the liberated hydrogen chloride was excluded, in the phenolyses without an added base the major products are the 1-phenylethyl ethers of the respective phenols with net retained configurations and the minor products are the o-and p-1-phenylethylated phenols with net inverted configurations. The hydrogen chloride rearrangement of the optically active 1-phenylethyl ethers of the respective phenols proceeded rapidly to give o-1-phenylethylated phenols with predominantly retained configuration..." @default.
- W2070291004 created "2016-06-24" @default.
- W2070291004 creator A5016677481 @default.
- W2070291004 creator A5043194175 @default.
- W2070291004 creator A5047822717 @default.
- W2070291004 date "1974-07-01" @default.
- W2070291004 modified "2023-10-17" @default.
- W2070291004 title "Stereochemical Studies on the Nuclear Alkylation of Phenols with 1-Phenylethyl Chloride and the Acidic Rearrangement of the 1-Phenylethyl Ethers of Phenols in the Phenolic Solvents" @default.
- W2070291004 cites W1971512413 @default.
- W2070291004 cites W1977468785 @default.
- W2070291004 cites W1982429125 @default.
- W2070291004 cites W2007793352 @default.
- W2070291004 cites W2022990090 @default.
- W2070291004 cites W2064121744 @default.
- W2070291004 cites W2093725053 @default.
- W2070291004 cites W2157634496 @default.
- W2070291004 cites W2328313871 @default.
- W2070291004 cites W2331221015 @default.
- W2070291004 cites W2333373536 @default.
- W2070291004 cites W2333403754 @default.
- W2070291004 doi "https://doi.org/10.1246/bcsj.47.1770" @default.
- W2070291004 hasPublicationYear "1974" @default.
- W2070291004 type Work @default.
- W2070291004 sameAs 2070291004 @default.
- W2070291004 citedByCount "5" @default.
- W2070291004 crossrefType "journal-article" @default.
- W2070291004 hasAuthorship W2070291004A5016677481 @default.
- W2070291004 hasAuthorship W2070291004A5043194175 @default.
- W2070291004 hasAuthorship W2070291004A5047822717 @default.
- W2070291004 hasBestOaLocation W20702910041 @default.
- W2070291004 hasConcept C155647269 @default.
- W2070291004 hasConcept C161790260 @default.
- W2070291004 hasConcept C164361826 @default.
- W2070291004 hasConcept C178790620 @default.
- W2070291004 hasConcept C185592680 @default.
- W2070291004 hasConcept C2777728882 @default.
- W2070291004 hasConcept C2778695967 @default.
- W2070291004 hasConceptScore W2070291004C155647269 @default.
- W2070291004 hasConceptScore W2070291004C161790260 @default.
- W2070291004 hasConceptScore W2070291004C164361826 @default.
- W2070291004 hasConceptScore W2070291004C178790620 @default.
- W2070291004 hasConceptScore W2070291004C185592680 @default.
- W2070291004 hasConceptScore W2070291004C2777728882 @default.
- W2070291004 hasConceptScore W2070291004C2778695967 @default.
- W2070291004 hasIssue "7" @default.
- W2070291004 hasLocation W20702910041 @default.
- W2070291004 hasOpenAccess W2070291004 @default.
- W2070291004 hasPrimaryLocation W20702910041 @default.
- W2070291004 hasRelatedWork W2019919093 @default.
- W2070291004 hasRelatedWork W2134929738 @default.
- W2070291004 hasRelatedWork W2317452413 @default.
- W2070291004 hasRelatedWork W2321220820 @default.
- W2070291004 hasRelatedWork W2335829272 @default.
- W2070291004 hasRelatedWork W2399340188 @default.
- W2070291004 hasRelatedWork W2402425649 @default.
- W2070291004 hasRelatedWork W2951803252 @default.
- W2070291004 hasRelatedWork W2953026840 @default.
- W2070291004 hasRelatedWork W4252524260 @default.
- W2070291004 hasVolume "47" @default.
- W2070291004 isParatext "false" @default.
- W2070291004 isRetracted "false" @default.
- W2070291004 magId "2070291004" @default.
- W2070291004 workType "article" @default.