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• W2070291781 endingPage "138" @default.
• W2070291781 startingPage "125" @default.
• W2070291781 abstract "He I photoelectron spectra have been recorded for the reactions F+CH3OH, F+CH3SH and F+CH3OCH3 and bands associated with the primary reaction products are identified. The known first photoelectron band of CH2OH, with an adiabatic ionization energy (IE) of (7.56±0.01) eV, and a sharp band with an adiabatic IE of (10.72±0.01) eV have been observed early in the F+CH3OH reaction. This latter feature is assigned to the first photoelectron band of CH3O. The corresponding band of CD3O has been observed in the F+CD3OH and F+CD3OD reactions and is found to be unchanged in shape and position from the first band of CH3O. Similarly, the first photoelectron bands of CH3S and CH2SH have been identified in spectra recorded for the F+CH3SH reaction. The CH3S first photoelectron band is sharp and has an adiabatic IE of (9.25±0.02) eV whereas the CH2SH first band is broad and has an adiabatic IE of (7.52±0.03) eV. These values are in excellent agreement with ionization energies obtained from recent photoionization mass spectrometric studies and molecular orbital calculations on these short-lived molecules. In addition, a broad band observed at low reaction times in the F+CH3OCH3 reaction, with an adiabatic IE of (7.04±0.02) eV, is assigned to the first ionization of the CH2OCH3 radical. The first band of the CD2OCD3 isotopomer has also been identified in the corresponding F+CD3OCD3 reaction. A comparison is made with the results obtained for the F+CH3SCH3 reaction in which the first photoelectron band of CH2SCH3 was recorded." @default.
• W2070291781 created "2016-06-24" @default.
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• W2070291781 date "1995-07-01" @default.
• W2070291781 modified "2023-10-16" @default.
• W2070291781 title "Primary products of the reactions of fluorine atoms with CH3OH, CH3SH and CH3OCH3 studied with ultraviolet photoelectron spectroscopy" @default.
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• W2070291781 doi "https://doi.org/10.1016/0368-2048(94)02253-4" @default.
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