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- W2070295579 abstract "Experiments extending the temperature domain of the ammonium perchlorate (A.P.) linear pyrolysis studies were performed by a method derived from the porous plate technique but substituting an electrically heated grid. The temperature region which was explored extended from 590° to 1540°K and the pressure region from 0.026 to 26 atm. In the most interesting region, above 910°K, the results are well represented by an empirical relation which expresses a dependency of the regression rate upon the pressure. The pressure sensitivity depends upon the surface temperature and vice versa. Below 21 atm, at a given pressure, the regression rate seems to increase with increasing temperature, whereas it decreases above 21 atm. The concept of free pyrolysis (adiabatic) is introduced, as opposed to forced pyrolysis (diabatic). Ordinary combustion of A.P. under pressure can be assimilated to a free pyrolysis and the agreement between the free pyrolysis data and the burning rate data is excellent. The burning rate or free pyrolysis rate is then proportional to the 0.5th power of the pressure at low pressures (1 to 5 atm) and to the 0.9th power at high pressures. At low temperaturs, the regression rate is not sensitive to pressure." @default.
- W2070295579 created "2016-06-24" @default.
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- W2070295579 date "1969-01-01" @default.
- W2070295579 modified "2023-09-28" @default.
- W2070295579 title "High temperature pyrolysis of ammonium perchlorate" @default.
- W2070295579 doi "https://doi.org/10.1016/s0082-0784(69)80435-2" @default.
- W2070295579 hasPublicationYear "1969" @default.
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