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- W2070296477 abstract "ABSTRACT Various fluoro-functionalized aromatic 1,3,5-triazine monomers were prepared. A series low molar mass and poly4l,3,5-triazine)-ethers were synthesized by a condensation reaction. The polymers as well as the low molar mass compounds have excellentthermal stability and are amorphous. In order to examine the potential to apply these compounds in organic electroluminescentdevices, the redox properties were studied by cyclic voltammetiy. It was found that the monomers have high electron affInity andreach LUMO values in the range of -2.7 to -3.1 eV. Additional high oxidation stability with HOMO values lower than -6.4 eV follows hole blocking capabilities. This opens the possibility to utilize 1,3,5-tnazine containing materials as electron injecting/hole blocking layer in LEDs. First LED results are in agreement to these high electron affinities.Keywords: 1,3,5-triazine, aromatic ethers, electron transport, cyclic voltanimetiy, LEDs, PPV 1. INTRODUCTION LEDs based on amorphous organic compounds have compared to inorganic LEDs primarily the advantage of an easyfabrication of large area devices utilizing well estabilshed solvent casting techniques. Materials for such devices have to fuilfill" @default.
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- W2070296477 date "1998-01-01" @default.
- W2070296477 modified "2023-09-26" @default.
- W2070296477 title "Aromatic polyethers with 1,3,5-triazine units as hole blocking/electron transport materials in leds" @default.
- W2070296477 cites W1993940760 @default.
- W2070296477 doi "https://doi.org/10.1002/masy.19981250113" @default.
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