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- W2070298110 abstract "INFLUENCE OF HYDROGEN COVERAGE ON THE HYDROGENATION MECHANISM OF ACRYLONITRILE Thomas C. Franklin and Masahiko Naito Chemistry Department, Baylor University, Waco, Texas. (Received in USA 5 August 1968; received in UK for publication 11 October 1968) The electrolytic hydrodimerization of acrylonitrile has been the subject of several recent investigations (1 4). The side reactions usually produce either the saturated nitrile or amine. The dimerixation is expected to involve an electron transfer process while the side reactions probably involve direct addition of hydrogen atoms to the molecule. It is generally stated that acrylonitrile is hydrogenated catalytically on the surface of metals of relatively low hydrogen wervoltage such as platinum, palladium and nickel, but is hydrogenated electrochemically on the surface of metals of high hydrogen overvoltage such as mercury. Recently (5) a. technique was described for distinguishing between reduction by an electron transfer mechanism and reduction by hydrogen addition on metals with relatively low hydrogen overvoltages. This technique consisted of relating the potential of the hydrogen electrode to the fraction of the surface covered with hydrogen. It was shown that if the compound is reduced by catalytic addition of atomic hydrogen the potential of the electrode is given by the following expression at 25'C, 0 E-E .059 log 0 1-8, (I)" @default.
- W2070298110 created "2016-06-24" @default.
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- W2070298110 date "1968-01-01" @default.
- W2070298110 modified "2023-09-27" @default.
- W2070298110 title "Influence of hydrogen coverage on the hydrogenation mechanism of acrylonitrile" @default.
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- W2070298110 doi "https://doi.org/10.1016/s0040-4039(00)76334-9" @default.
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