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- W2070310282 abstract "The synthesis and derivatization of copoly(styrene-2,4,5-trichlorophenyl acrylate) (1) is described to obtain a new class of reactive and electroreactive polymers. Thus, the equimolar copolymerization of styrene and 2,4,5-trichlorophenyl acrylate in chlorobenzene, at 60°C in the presence of AIBN for 15 h, furnished the predominantly alternate copolymer in nearly quantitative yields. Complete displacement of the trichlorophenoxy (activating) groups by functional group carrying nuceophiles, for example 4-(2-aminoethyl)pyridine, histidine methyl ester, or 3-formamidopropanol, was carried out to produce the corresponding polymer derivatives with relatively high degrees of functionality. Alternatively, 1 was first partially reacted with a simple (structural) amine, such as morpholine or benzylamine, followed by reaction with a functional group carrying amine, or vice versa, to produce reactive polymers with relatively lower degrees of functionality, for example, anthraquinone, triethylenetriamine, or di-(2-hydroxyethyl)amine. Reaction of 1 with haloethylamines produced halogen carrying oligoimine grafts on the polymer backbone. The above named formamido polymer was further transformed to its isonitrile derivative. The hydroxy and halogen containing polymers were converted to the corresponding diphenylphosphine derivatives (the former via tosylation). The polymers carrying isocyano, amine, bidentate phosphine, or multidentate amine/phosphine ligands were reacted with Pd(II) or Cu(II), to obtain polymeric complexes containing ca. 3–20% complexed metal. The covalent attachment of polymers to amine-carrying electrodes, by active ester aminolysis, or by four component condensation is also briefly described." @default.
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- W2070310282 date "1986-05-01" @default.
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- W2070310282 title "Chemical modification of copoly(styrene-2,4,5-trichlorophenyl acrylate) to give polymers which are potentially electroactive" @default.
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- W2070310282 doi "https://doi.org/10.1016/0032-3861(86)90138-2" @default.
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