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- W2070316820 abstract "For the first time, simple N-tosyl aryl aldimines, prepared from the condensation of tosyl amide and aromatic aldehydes, can be used as substrates in the rhodium catalyzed 1,2-addition reaction using alkenylboron nucleophiles. In the presence of 1.5 mol % of [RhCl(1e)]2, enantioselective addition of various potassium alkenyltrifluoroborates to aryl aldimines furnished the corresponding chiral allylic amines in 73–96% yield and 72–>99.5% ee. Notably, this method efficiently provides the di-, tri-, and tetrasubstituted allylic N-tosyl amines with high asymmetric induction." @default.
- W2070316820 created "2016-06-24" @default.
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- W2070316820 date "2013-12-30" @default.
- W2070316820 modified "2023-10-07" @default.
- W2070316820 title "Highly Enantioselective Rh-Catalyzed Alkenylation of Imines: Synthesis of Chiral Allylic Amines via Asymmetric Addition of Potassium Alkenyltrifluoroborates to <i>N</i>-Tosyl Imines" @default.
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- W2070316820 doi "https://doi.org/10.1021/ol4035897" @default.
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