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- W2070326148 abstract "Activation enthalpy-entropy correlations for the experimental data available for dehydrochlorination of chloroalkanes and chloroalkenes in the gas and in the liquid phase or non-polar solvents show that this reaction has two possible mechanisms: chloroalkanes, 3-chloro-1-alkenes and trans 1-alkyl-3-chloro-1-alkenes (gas phase) eliminate HCl through a transition state of four centers requiring a synperiplanar conformation of the group (Scheme 1). Cis 1-alkyl-3-chloro-1-alkenes and trans 1-alkyl-3-chloro-1-alkenes (liquid phase) and conjugated 1-alkyl-5-chloro-1,3-alkadienes eliminate HCl through a transition state of six centers requiring a cis configuration of the double bond (Scheme 2). The activation parameters for the elementary reactions of PVC degradation fit on the same correlation lines supporting, for the initiation reaction, a mechanism involving a transition state of four centers and for propagation and termination reactions, a mechanism involving a transition state of six centers." @default.
- W2070326148 created "2016-06-24" @default.
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- W2070326148 date "1994-01-01" @default.
- W2070326148 modified "2023-10-16" @default.
- W2070326148 title "Degradation and stabilization of poly(vinyl chloride). III. Correlation of activation enthalpies and entropies for dehydrochlorination of chloroalkanes, chloralkenes and poly(vinyl chloride)" @default.
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- W2070326148 doi "https://doi.org/10.1016/0141-3910(94)90202-x" @default.
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