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• W2070330556 abstract "All experimental attempts to identify the tert-butyl carbenium ion in zeolites have been unsuccessful. Calculations with the hybrid MP2:DFT method predict that this ion is less stable than the isomeric surface species isobutene, isobutoxide, and tert-butoxide, but once it has been formed as an intermediate it will survive long enough (59 μs) to be detected by laser spectroscopy (see picture; O red, Si yellow, Al magenta, C green)." @default.
• W2070330556 created "2016-06-24" @default.
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• W2070330556 date "2010-06-16" @default.
• W2070330556 modified "2023-10-18" @default.
• W2070330556 title "The tert-Butyl Cation in H-Zeolites: Deprotonation to Isobutene and Conversion into Surface Alkoxides" @default.
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• W2070330556 doi "https://doi.org/10.1002/anie.200907015" @default.
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