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- W2070339959 abstract "The lateral growth rate and growth shape morphology of isotactic polybutene-1 tetragonal crystals were investigated for crystallization from the melt at temperatures of 68–101 °C. The growth rate of tetragonal crystals shows supercooling dependence derived from the nucleation theory, and a regime II–III transition is observed at temperatures of 77–82.2 °C. The morphology of single crystals is rounded below temperatures of 77–85 °C, while the growth shape has a faceted morphology at a higher crystallization temperature of 100 °C. The kinetic roughening transition occurs between 77 and 85 °C. The regime II growth mode is observed above 82.2 °C and proceeds by multiple nucleation on the faceted growth front, while the regime III growth mode is observed below 77 °C and proceeds by rough surface growth on the kinetically roughened growth front. The observed regime II–III transition can therefore be explained by the morphology transition of crystal growth shape." @default.
- W2070339959 created "2016-06-24" @default.
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- W2070339959 date "2014-02-01" @default.
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- W2070339959 title "Regime II–III transition in isotactic polybutene-1 tetragonal crystal growth" @default.
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- W2070339959 doi "https://doi.org/10.1016/j.polymer.2013.12.044" @default.
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