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- W2070350649 abstract "In the adenosine-putrescine (1,4-diaminobutane) system, noncovalent interaction between bioligands was found to occur. The equilibrium constant of the adduct formation reaction is equal to log K = 1.51. The ligand-ligand interaction is not observed to occur in the cytidine/putrescine system. On the basis of computer analysis of potentiometric titration data for ternary systems: Cu(II)/adenosine (or cytidine)/putrescine, the stability constants of the complexes were determined and their distribution was presented. It was found that in the cytidine-containing systems, mixed-ligand complexes are not formed. Spectral studies indicate characteristic differences in the mode of coordination in the adenosine ternary systems relative to binary systems. A presence of putrescine contributes to the broadening (relative to the Cu(II)/Ado binary system) of pH range for the coordination dichotomy to occur. Differences in the coordination mode between the synthesized solid complexes and complexes in solution have been identified. Likewise in solution, cytidine does not form solid mixed-ligand complexes with Cu(II) and putrescine." @default.
- W2070350649 created "2016-06-24" @default.
- W2070350649 creator A5000336482 @default.
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- W2070350649 date "1996-05-01" @default.
- W2070350649 modified "2023-09-27" @default.
- W2070350649 title "Investigations of binding sites and stability of complexes formed in ternary Cu(II)/adenosine or cytidine/putrescine systems" @default.
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- W2070350649 doi "https://doi.org/10.1016/0162-0134(95)00120-4" @default.
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