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- W2070361878 abstract "The equilibrium diagram of the system bismuth-palladium has been studied in the region 0–65 at.-% Pd by thermal analysis and microscopical methods. The freezing point of bismuth is depressed by the addition of palladium and sinks to a eutectic at 5.83 at.-% Pd and 256°C. The liquidus then rises to 485.4°C, at which temperature the compound “Bi2Pd” melts without change of composition. The compound BiPd gives rise to a pronounced maximum in the liquidus curve at 618°C, and there is a palladium-rich eutectic at 577°C. At low temperatures the composition of the “Bi2Pd” phase is about 34 at.-% Pd. It undergoes a transformation at 380°C, in contrast to the earlier work of Zhuravlev And Zhdanov, according to whom the transformation took place at 200°C. There is a remarkable resemblance between the equilibrium diagrams of the systems Pd-Sb and Pd-Bi. Both give rise to compounds of the type PdX2, the melting points of the Sb-compounds being systematically higher." @default.
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- W2070361878 date "1959-04-01" @default.
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- W2070361878 title "The equilibrium diagram of the system bismuth-palladium" @default.
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- W2070361878 doi "https://doi.org/10.1016/0022-5088(59)90057-8" @default.
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