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- W2070362244 abstract "Diazoalkane complexes [RuCl(N2CAr1Ar2)(η6-p-cymene)P]BPh4 [Ar1 = Ph; Ar2 = Ph or p-tolyl; P = PPh(OEt)2 or P(OEt)3] were prepared by allowing p-cymene complexes RuCl2(η6-p-cymene)P to react with diaryldiazoalkane Ar1Ar2CN2. Treatment of the triisopropylphosphine complex RuCl2(η6-p-cymene)(PiPr3) with 9-diazofluorene yielded the (η5-alkoxyfluorenyl)(η6-p-cymene)-sandwich derivative [Ru(η5-RO-fluorenyl)(η6-p-cymene)]BPh4 (R = Me, Et). The complexes were characterized spectroscopically (IR and 1H, 13C, 31P NMR) and by X-ray crystal structure determination of the [Ru(η5-EtO-fluorenyl)(η6-p-cymene)]BPh4 derivative." @default.
- W2070362244 created "2016-06-24" @default.
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- W2070362244 date "2009-07-02" @default.
- W2070362244 modified "2023-09-24" @default.
- W2070362244 title "Preparation of (η<sup>5</sup>-Alkoxyfluorenyl)(η<sup>6</sup>-<i>p-</i>Cymene)-Sandwich Ruthenium(II) Complexes" @default.
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- W2070362244 doi "https://doi.org/10.1021/om900350n" @default.
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