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- W2070383106 abstract "Abstract Transmission electron microscopy (TEM) of yttria (Y2O3)-cubic-stabilized zirconia with an yttria content between 24 and 32 mol% reveals diffuse electron scattering. Analysis of the diffuse intensity maxima in electron diffraction patterns recorded with the incident electron beam along (112)c or (110)c zone axes suggests that they originate from incipient microdomains of the δ phase', a superstructure with the composition Zr3Y4O12. A compound with this composition has been observed before, however, for Y2O3 concentrations substantially higher (40 mol% or greater) than in our case. The microdomains are probably platelets and must have a diameter of less than 10 nm, rendering them hard to detect in TEM images. Apart from the δ phase, we have considered two other superstructures to explain the experimental observations, the pyrochlore type phase Zr2Y2O7 and the structure of the C-type rare-earth oxide Y2O3. However, our data allow us to rule out these superstructures as the main source of diffuse electron scattering." @default.
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- W2070383106 date "2001-07-01" @default.
- W2070383106 modified "2023-10-18" @default.
- W2070383106 title "Origin of diffuse electron scattering in yttria-cubicstabilized zirconia single crystals with 24–32 mol% yttria" @default.
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- W2070383106 doi "https://doi.org/10.1080/01418610010019053" @default.
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