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- W2070401980 abstract "The toxicity of chlorine trifluoride (ClF3) is based primarily on its corrosive effects on surfaces of contact. The damage caused by CIF3 is in part a function of its diverse hydrolysis products, which may form in varying proportions in the atmosphere, in pulmonary gases or during decontamination procedures. In the vapor phase, CIF3 may decompose to ClF, Cl2, ClOF, ClO2F, ClO3F, ClO2 and HF, depending on the availability of water. Of these, Cl2, HF and ClO2 are probably of greatest significance. Inhalation exposure of rats to 800 ppm ClF3 for 15 min was always lethal and 13 min of contact was usually survived. Four-hundred ppm was usually lethal after 35 min of exposure. ClF3, given ip in doses up to 400 μmol/kg, was not lethal although this high dose is considerably greater than the calculated maximum inhaled dose. ClF3 exposures resulted in severe mucosal inflammation and burning of the skin, followed by corneal ulceration. Pulmonary release of 14CO2 from injected [14C]bicarbonate was decreased after ClF3 inhalation, as was blood pH, indicating pulmonary impairment. Of the principal hydrolysis products considered, ClO2F decomposes too rapidly in the presence of water vapor for study, ClO3F was always lethal at exposures of 5000 ppm × 15 min and 2000 ppm × 40 min with extensive methemoglobin formation, and essentially nonlethal at 2000 ppm × 25 min and 1000 ppm × 60 min. ClO2 lethality is comparable to that of ClF3 on a chlorine equivalent basis. ClF3 lethality is similarly comparable to that of HF, on a fluorine equivalent basis. Predictions are made of the behavior of ClF3 atmospheres, and of the expected dominant products in such atmospheres under various conditions." @default.
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- W2070401980 date "1974-03-01" @default.
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- W2070401980 title "Toxic properties of chlorine trifluoride" @default.
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- W2070401980 doi "https://doi.org/10.1016/0041-008x(74)90032-5" @default.
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