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- W2070404048 abstract "A new rearrangement was discovered in the reaction of o-carboranecarboxylic acid chlorides with NaFe(CO)2C5H5-π which led to [exo-(substituted-o-carboranyl)-cyclopentadiene]iron tricarbonyls. This rearrangement involves the formation of σ-acyl complex o-R-CB10H10CCOFe(CO)2C5H5-π. Thermal transformations of these compounds to be binuclear iron complexes and their further conversion into the respective ferrocenes were investigated. It is interesting to note that 1,1′-(1,2-o-carboranylene)ferrocene has a rather large dihedral angle between the cyclopentadienyl ring planes. Reactions of m-carboranecarboxylic and o-carboranylacetic acid chlorides with NaFe(CO)2C5H5-π resulted in the formation of σ-acyliron complexes which gave CO on heating and were transformed to the respective σ-iron derivatives." @default.
- W2070404048 created "2016-06-24" @default.
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- W2070404048 date "1971-02-01" @default.
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- W2070404048 title "A rearrangement in the reaction of o-carboranecarboxylic acid chlorides with NaFe(CO)2C5H5-π" @default.
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- W2070404048 doi "https://doi.org/10.1016/s0022-328x(00)82999-x" @default.
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