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- W2070475634 abstract "Raman spectra of purified ${mathrm{C}}_{60}$ single crystals are measured over a wide temperature range. It is found that above 400 K the high-frequency ${mathit{A}}_{mathit{g}}$ mode (pentagonal pinch mode) changes in frequency and becomes sharp compared with the ${mathit{A}}_{mathit{g}}$ mode at room temperature. This spectral change is reversible. The results indicate that structural change occurs and the intermolecular interaction for each ${mathrm{C}}_{60}$ molecule is isotropic above 400 K. A reversible spectral change is observed as the intensity of the excitation laser varies. The similarity between the spectral change at 400 K and the spectral change at high laser intensity levels suggests that the photoinduced spectral change observed in the present study is due to the thermal effects of laser irradiation." @default.
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- W2070475634 date "1993-09-15" @default.
- W2070475634 modified "2023-09-25" @default.
- W2070475634 title "Raman study of a structural phase transition in<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>C</mml:mi></mml:mrow><mml:mrow><mml:mn>60</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>crystals" @default.
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- W2070475634 doi "https://doi.org/10.1103/physrevb.48.8510" @default.
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