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- W2070485498 abstract "An analysis of the equation TM=T0 (n+a) / (n+b) is made in order to determine the convergence temperature T0 of the melting temperatures of the n‐paraffins from C44 to C100. A good fit is obtained using T0=414.3°K, a=—1.5, and b=5.0. This value of T0 (414.3°K=141.1°C) has an estimated total uncertainty of ±2.4°K and is proposed as the correct value of the equilibrium melting temperature of polyethylene. It is shown that presently available data do not permit accurate extrapolation of the n‐paraffin heats and entropies of fusion to the polymer limit." @default.
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- W2070485498 date "1962-05-15" @default.
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- W2070485498 title "Extrapolation of the Orthorhombic<i>n</i>‐Paraffin Melting Properties to Very Long Chain Lengths" @default.
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- W2070485498 doi "https://doi.org/10.1063/1.1732337" @default.
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