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- W2070487777 abstract "The effect on micellar structure of changing the solvent from H/sub 2/O to D/sub 2/O for alkyltrimethylammonium bromide (C/sub n/TAB; C/sub n/TAB triple bond C/sub n/H/sub 2n+1/N(CH/sub 3/)/sub 3/Br, with n = 12, 14, and 16) has been examined. The energetics of micellization have been determined by measuring critical micelle concentrations by using surface tensiometry. The micellar structure has been elucidated through the use of small-angle neutron scattering (SANS). It was found that there is a solvent isotope effect that is small for C/sub 12/TAB but increases with n. This effect is manifested mainly by an increase in aggregation number and is attributed to solvent-hydrocarbon interactions of the dissolved monomers. The fractional charge of the micelle is not altered by the isotopic composition of the solvent. C/sub n/TAB micelles are found to be drier than are micelles formed by the corresponding sodium alkyl sulfates, and this results in a larger solvent effect for the quaternary ammonium bromides." @default.
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- W2070487777 date "1987-08-27" @default.
- W2070487777 modified "2023-10-01" @default.
- W2070487777 title "Solvent isotope effects on alkytrimethylammonium bromide micelles as a function of alkyl chain length" @default.
- W2070487777 doi "https://doi.org/10.1021/j100302a024" @default.
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