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- W2070491556 abstract "Abstract A method using isotopic dilution of carrier‐free sulfur (35S) for determining adsorbed sulfate (SO4 2‐) in soil samples from B horizons of podsolized soils was compared with an extraction of SO4 2‐ by 10 mM calcium dihydrogen phosphate [Ca(H2PO4)2]. The two methods gave comparable results for flesh soil samples while the extraction method resulted in significantly higher amounts of adsorbed SO4 2‐ when using air‐dried samples. Since the 35S method assumes equilibrium between adsorbed SO4 2‐ and SO4 2‐ in solution, these results are evidence of complete exchangeability of adsorbed SO4 2‐ extracted with Ca(H2PO4)2 in fresh soil samples. It was thus concluded that the extraction method is a useful method when determining adsorbed SO4 2‐ in equilibrium with the soil solution in these soils. The 35S reached equilibrium with the soil solution within 2 h. The difference between the methods when using air‐dried samples indicates that part of the adsorbed SO4 2‐ is irreversibly bound to the soil during air‐drying. Furthermore, it is recommended that the amount of SO4 2‐ determined in an extraction with water should be expressed as an intensity variable, i.e., SO4 2‐ activity, rather than a capacity variable." @default.
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- W2070491556 title "The determination of adsorbed sulfate with isotopic dilution of sulfur (<sup>35</sup>S) compared with calcium dihydrogen phosphate extraction" @default.
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- W2070491556 doi "https://doi.org/10.1080/00103629409369031" @default.
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