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- W2070495564 abstract "Abstract A series of 1,3-dioxanyl vinyl acetals were readily synthesized from the corresponding dioxanone by a reduction and in situ acylation followed by Petasis olefination. Treatment of these vinyl acetals with BF3·OEt2 results in an O to C rearrangement to form anti-3,5-dihydroxyketones while a mixture of Me3Al and BF3·OEt2 provides the corresponding syn relationship via a stereoretentive rearrangement." @default.
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- W2070495564 date "2003-11-01" @default.
- W2070495564 modified "2023-10-15" @default.
- W2070495564 title "1,3-Polyol arrays via the stereoselective rearrangement of vinyl acetals" @default.
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- W2070495564 doi "https://doi.org/10.1016/j.tet.2003.03.004" @default.
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