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- W2070542015 abstract "Borohydride salts have been studied in various solvents by infrared and n.m.r. spectroscopy. Solutions in water containing HOD in low concentration exhibit an O—D stretching frequency profile indicative of relatively strong hydrogen bonding to the anion, comparable with that for chloride ions. The asymmetric B—H stretching band for BH–4(v3) is a broad singlet in water (∼2270 cm–1) but shifts strongly to lower frequencies as basic aprotic solvents, such as hexamethylphosphoramide, are added. This is again indicative of “hydrogen-bonding” to the anions by water." @default.
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- W2070542015 date "1977-01-01" @default.
- W2070542015 modified "2023-09-27" @default.
- W2070542015 title "Solvation spectra. Part 53.—Infrared and nuclear magnetic resonance studies of the tetrahydroborate anion in various pure solvents and binary aqueous mixtures" @default.
- W2070542015 doi "https://doi.org/10.1039/f19777301253" @default.
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