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- W2070596688 abstract "The enthalpies of combustion (by micro bomb calorimetry) and sublimation at 298.15 K have been determined for bullvalene. The derived enthalpies of formation of bullvalene in the crystalline and gaseous states at 298.15 K are: ΔHfo(c) = (262.3 ± 3.3) kJ mol−1 and ΔHfo(g) = (334.1 ± 3.3) kJ mol−1, respectively. The derived apparent strain energy [S] of bullvalene amounts to 146 kJ mol−1. The [S] term is shown to be consistent with recent findings that in bullvalene there is substantial conjugative interaction between the cyclopropane ring and the π electrons of the double bonds." @default.
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- W2070596688 date "1981-07-01" @default.
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- W2070596688 title "Enthalpy of formation and strain energy of bullvalene (tricyclo[3.3.2.04, 6]deca-2,7,9-triene); a calorimetric study" @default.
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- W2070596688 doi "https://doi.org/10.1016/0021-9614(81)90039-2" @default.
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