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- W2070603309 abstract "The influence of rare-earth cations on the preparation and properties of polyaniline (PANI) was investigated in the presence of a magnetic field. It was found that the addition of rare-earth cations can greatly increase the polymerization rate of PANI in the following order: Tb3+>Nd3+>Ce3+. When a parallel magnetic field (Bp) was imposed with respect to the electrode surface, the maximum polymerization rate was obtained at Bp=0.5 T. Whereas, in a perpendicular magnetic field (Bs), the rate was accelerated as the magnetic flux density rose. The conductivity of PANI/Tb3+/Bp=0.7 T film was 115.4 S cm−1 which, as expected, is higher by about an order of magnitude as compared to the parent PANI film without the effects of rare-earth cations and magnetic field. Meanwhile, the X-ray diffraction patterns and electrochemical impedance spectroscopy indicated an increase of crystallinity and a more-ordered arrangement of the polymer chains with a concurrent increase in the capacitance, and a decrease in the charge transfer resistance and the ohmic resistance in the presence of rare-earth cations and magnetic field." @default.
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- W2070603309 date "1997-06-01" @default.
- W2070603309 modified "2023-10-09" @default.
- W2070603309 title "Improved conductivity and electrical properties of polyaniline in the presence of rare-earth cations and magnetic field" @default.
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- W2070603309 doi "https://doi.org/10.1016/s0379-6779(97)03851-4" @default.
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