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- W2070604503 abstract "Rate constants for the reaction of OH radicals and Cl atoms with CH3ONO2, C2H5ONO2, n-C3H7ONO2, n-C4H9ONO2, and n-C5H11ONO2 have been determined at 298 ± 2 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute-rate technique or pulse radiolysis combined with kinetic spectroscopy and a conventional photolytic relative-rate method. The Cl rate constants were measured using only the relative-rate method. Evidence is presented from the kinetic studies that reaction of OH radicals with alkyl nitrates may involve both addition and abstraction pathways. The data show that the —ONO2 group substantially decreases the rate constant for H-atom abstraction by OH radicals from groups bonded to the —ONO2 group and also decreases that for groups in the β position. Similar resuls were found for the reaction of Cl atoms with these compounds. The results are discussed in terms of reactivity trends." @default.
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- W2070604503 date "1991-03-01" @default.
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- W2070604503 title "An absolute- and relative-rate study of the gas-phase reaction of OH radicals and Cl atoms with n-alkyl nitrates" @default.
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- W2070604503 doi "https://doi.org/10.1016/0009-2614(91)87051-c" @default.
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