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- W2070634230 abstract "A new cyanide-bridged FeIIIMnIII binuclear complex {[Fe(bpy)(CN)4][Mn(TPP)(CH3OH)]}·CH3OH (1) [bpy = 2,2′-bipyridine, TPP = tetraphenylporphyrin] and an ion-pair compound {[Fe(bpy)(CN)4][Mn(TNPP)(CH3OH)2]}·2CH3CN (2) [TNPP = tetra(p-nitrophenyl)porphyrin] have been synthesized based on two manganese(III)-porphyrin precursors [Mn(L)(H2O)2]ClO4 (L = TPP and TNPP) and one cyanide-containing building block K[Fe(bpy)(CN)4]. The crystal structures of the two complexes have been determined by X-ray single crystal diffraction. Magnetic study reveals that complex 1 exhibits weak antiferromagnetic coupling between low-spin Fe(III) and high-spin Mn(III) through the cyanide bridge." @default.
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- W2070634230 date "2012-05-01" @default.
- W2070634230 modified "2023-10-16" @default.
- W2070634230 title "Syntheses, crystal structures and magnetic properties of two FeIII–MnIII complexes based on manganese(III)-porphyrin and tetracyanideferrite(III) building blocks" @default.
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- W2070634230 doi "https://doi.org/10.1016/j.inoche.2012.02.012" @default.
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