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• W2070654319 startingPage "151" @default.
• W2070654319 abstract "Recent advances in MALDI of synthetic polymers is reviewed. The review will be limited in scope and not comprehensive, but will focus on areas where there has been significant progress and/or where some opportunities lie. Ion formation mechanisms for polymers still remain somewhat elusive. Advances in studies of protonation mechanisms need to be extended to synthetic polymers to answer the question why the latter seem to largely prefer cationization over proton addition. There has been significant progress in the MS/MS of synthetic polymers, mostly by collision-induced dissociation and post-source decay. New and interesting results have been reported, but this area requires further investigation. The combination of MALDI with separation methods for synthetic polymers shows considerable potential and various applications are appearing. Of particular interest is coupling to size-exclusion chromatography and how to perform measurements on-line and in real time. Determination of polymer structure is possible including end-group analysis, derivatization, and analysis for embedded chain segments. Finally, novel solid-state supports have been reported, offering great potential for MALDI generally and polymer MALDI specifically." @default.
• W2070654319 created "2016-06-24" @default.
• W2070654319 creator A5023324383 @default.
• W2070654319 creator A5060570221 @default.
• W2070654319 date "2003-03-01" @default.
• W2070654319 modified "2023-10-12" @default.
• W2070654319 title "MALDI of synthetic polymers—an update" @default.
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• W2070654319 doi "https://doi.org/10.1016/s1387-3806(02)00971-5" @default.
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