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- W2070679938 abstract "Abstract The addition of mixture of polystyrene‐ b ‐poly( N ‐isopropylacrylamide) (PS‐ b ‐PNIPAM) and polystyrene homopolymer ( h ‐PS) in tetrahydrofuran dropwise into water leads to nanoparticles with a PS core and a thermally sensitive PNIPAM shell. The effects of the ratio of the homopolymer to copolymer and temperature on the formation and stabilization of the dispersion were investigated by using a combination of static and dynamic laser light scattering. PNIPAM shell continuously collapses as temperature increases in the range 20–40 °C. Such formed particles are stable even at temperatures much higher than lower critical solution temperature (LCST ∼ 32 °C) of PNIPAM. Our results reveal that the area occupied per hydrophilic PNIPAM chain on the hydrophobic PS core remains nearly a constant regardless of the amount of h ‐PS in the polymer mixture. This clearly indicates that the surface area occupied per hydrophilic group is a critical parameter for stabilizing particles dispersed in water. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 48: 749–755, 2010" @default.
- W2070679938 created "2016-06-24" @default.
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- W2070679938 date "2010-02-18" @default.
- W2070679938 modified "2023-10-18" @default.
- W2070679938 title "Dispersion of polystyrene inside polystyrene-<i>b</i> -poly(<i>N</i> -isopropylacrylamide) micelles in water" @default.
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- W2070679938 doi "https://doi.org/10.1002/polb.21948" @default.
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