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- W2070682761 abstract "The new chiral auxiliary (R)-2-ethylthio-1-(phenylethyl)-(R)-binaphthyl phosphite, 1, and three stable Pd(0) olefin complexes containing this chelate, 2−4, have been synthesized. The structure of the maleic anhydride complex 3 has been determined by X-ray diffraction methods. Solution details for 2−4 and aspects of their dynamics have been elucidated via 2-D NMR spectroscopy. The fumaronitrile complex 2 exchanges intramolecularly, whereas the maleic anhydride and pentenedione derivatives, 3 and 4, respectively, exchange intermolecularly. Ligand 1 has been used as auxiliary in the Pd, Rh, and Ir regio- and enantioselective allylic alkylation reactions of PhCHCHCH(OAc)R, R = H, Me, Et, with the anion of dimethyl malonate. Modest to good selectivities are reported." @default.
- W2070682761 created "2016-06-24" @default.
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- W2070682761 date "1999-10-01" @default.
- W2070682761 modified "2023-10-14" @default.
- W2070682761 title "Chiral Phosphito−Thioether Complexes of Palladium(0). Comments on the Pd, Rh, and Ir Regio- and-Enantioselective Allylic Alkylations of PhCHCHCH(OAc)R, R = H, Me, Et" @default.
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- W2070682761 doi "https://doi.org/10.1021/om990452o" @default.
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