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- W2070688414 abstract "The lithium alkylamide-catalyzed addition reaction of p-substituted benzylamines with m- and p-divinylbenzene was examined in order to synthesize new styrene derivatives. Though divinylbenzene possesses two vinyl groups, 1 : 1 adducts, the N-(p-substituted benzyl)vinylphenethylamines (6, 8) were found to be prepared selectively. The reaction with styrene was also examined as a model reaction. From kinetic studies, the Hammett p values for the addition reaction of p-substituted benzylamines to the styrene, m-divinylbenzene and p-divinylbenzene, were −0.72, −0.67, and −1.1, respectively, at 50 °C." @default.
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- W2070688414 date "1992-04-01" @default.
- W2070688414 modified "2023-10-17" @default.
- W2070688414 title "Lithium Alkylamide-Catalyzed Addition Reaction of Alkylamines to Vinyl Monomers. III. Addition Reaction of<i>p</i>-Substituted Benzylamines to Styrene and Divinylbenzenes" @default.
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- W2070688414 doi "https://doi.org/10.1246/bcsj.65.1109" @default.
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