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- W2070696945 abstract "Abstract A systematic investigation of the influence of “pH” on the product identity from the CuII/H-Aib- l -Ala-OH (LH) reaction system is described, where H-Aib- l -Ala-OH is α-aminoisobutyryl- l -alanine. The pH variation has led to the synthesis of two discrete complexes, the structures of which have been determined by single-crystal X-ray crystallography. The “low pH” complex {[CuClL](H2O)2.5}n (1) is a 3D coordination polymer, in which the dipeptide monoanion L− behaves as a η1:η1:η1:μ2 ligand binding one CuII atom through its amino nitrogen and neutral peptide oxygen, and an adjacent CuII atom through one of its carboxylate oxygen. The “higher pH” complex {[Cu(H−1L)(EtOH)](EtOH)}n (2) is a chain (1D) compound, in which the dipeptide dianion H−1L2− uses its amino nitrogen, deprotonated peptide nitrogen and both carboxylate oxygens to bridge two metal centres." @default.
- W2070696945 created "2016-06-24" @default.
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- W2070696945 date "2005-12-01" @default.
- W2070696945 modified "2023-09-25" @default.
- W2070696945 title "The dipeptide H-Aib-l-Ala-OH ligand in copper(II) chemistry: Variation of product identity as a function of pH" @default.
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- W2070696945 doi "https://doi.org/10.1016/j.inoche.2005.09.008" @default.
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