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- W2070702931 abstract "The Arrhenius equation has been succesfully used in chemical reaction kinetics to describe the temperature dependence of the reaction rate constant. However, in a recent communication, D.J. Brown suggested that application of the Arrhenius equation in cellulose and wood pyrolysis studies is inappropriate. Based on results from isothermal pyrolysis studies in which heat and mass transfer effects were negligible, it has been shown that the Arrhenius equation adequately describes the temperature dependence of the overall degradation rate constant for cellulose and wood pyrolysis. Although the Arrhenius equation has little physical significance in solid-state reactions, it may be assumed as a two-parameter model to correlate the data thereby minimizing the number of adjustable parameters." @default.
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- W2070702931 date "1985-09-01" @default.
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- W2070702931 title "On the use of the arrhenius equation to describe cellulose and wood pyrolysis" @default.
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- W2070702931 doi "https://doi.org/10.1016/0040-6031(85)85227-8" @default.
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