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- W2070725052 abstract "Zinc chlorophyll derivatives possessing various substituents at the 3- and 13-positions were cleaved at the C19–C20 bond upon irradiation of an oxygen-saturated dichloromethane solution with visible light. The resulting photooxidation products were zinc complexes of linear tetrapyrroles which showed longer wavelength absorption bands in the near-infrared region than the visible Qy bands of the corresponding cyclic tetrapyrroles as the starting materials. Electron-withdrawing C13-substituents of the linear tetrapyrroles shifted the longest absorption maxima bathochromically, as observed in the cyclic tetrapyrroles. In contrast, more electron-withdrawing C3-substituents of the linear tetrapyrroles gave more hypsochromically shifted redmost maxima, which was the reverse of the substitution effect of the cyclic tetrapyrroles." @default.
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- W2070725052 date "2011-04-01" @default.
- W2070725052 modified "2023-09-28" @default.
- W2070725052 title "C3- and C13-substituent effects on electronic absorption spectra of linear tetrapyrroles produced by photooxidation of zinc chlorophyll derivatives" @default.
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- W2070725052 doi "https://doi.org/10.1016/j.jphotochem.2011.02.027" @default.
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