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• W2070739289 abstract "A versatile route to synthesize nanoporous crystalline metal oxides has been developed through the self-assembly of phloroglucinol–formaldehyde resol and tri-block copolymer templates. Materials were characterized by a complementary combination of X-ray diffraction, nitrogen sorption, and transmission electron microscopy. Metal oxides synthesized using this route have remarkably high surface area when compared with the commercial samples. The surface area of metal oxides decreased upon calcination at higher temperatures. However, the surface area was still much higher when compared with the commercial samples. TEM investigation reveals that upon calcination at higher temperature, the size of the crystal increased but the short range order was merely disturbed. The analyses show that the present method is suitable as a direct route to synthesize crystalline nanoporous metal oxides. Hydrogen bonding plays a key role in the preferential arrangement of porous metal–carbon structure in the domain of tri-block copolymer. The nanoporous metal oxides with ordered mesoporous structure, high surface area, and crystalline framework are expected to show significant improvement in catalysis and nano-technology." @default.
• W2070739289 created "2016-06-24" @default.
• W2070739289 creator A5007946809 @default.
• W2070739289 creator A5018001083 @default.
• W2070739289 date "2011-06-01" @default.
• W2070739289 modified "2023-10-14" @default.
• W2070739289 title "Synthesis of nanoporous metal oxides through the self-assembly of phloroglucinol–formaldehyde resol and tri-block copolymer" @default.
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• W2070739289 doi "https://doi.org/10.1016/j.jcis.2011.03.012" @default.
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