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• W2070755711 abstract "Known lanosterol synthase mutants produce monocyclic or tetracyclic byproducts from oxidosqualene. We describe Erg7 Tyr510 mutants that cause partial substrate misfolding and generate a tricyclic byproduct. This novel triterpene, (13αH)-isomalabarica-14(27),17E,21-trien-3β-ol, is the likely biosynthetic precursor of isomalabaricane triterpenoids in sponges. The results suggest the facile evolution of protective triterpenoids in sessile animals." @default.
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• W2070755711 date "2006-01-10" @default.
• W2070755711 modified "2023-09-23" @default.
• W2070755711 title "A Putative Precursor of Isomalabaricane Triterpenoids from Lanosterol Synthase Mutants" @default.
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• W2070755711 doi "https://doi.org/10.1021/ol052725j" @default.
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