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• W2070777744 abstract "A 13C isotopic effect was detected in the triplet sensitized photolysis of dibenzoyl peroxide. Analysis of 13C NMR spectra shows that the amount of 13C in position 1 of phenyl benzoate, the cage product, increase by 23 ± 5% in comparison with natural abundance. The observed isotopic effect considerably exceeds the known 12C13C kinetic isotopic effects. This effect is believed to be magnetic in origin and is explained in terms of the dependence of the recombination probabilities of radical pairs in the cage on the electron-nuclear hyperfine interaction." @default.
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• W2070777744 date "1977-05-01" @default.
• W2070777744 modified "2023-09-23" @default.
• W2070777744 title "A magnetic isotopic effect in the triplet sensitized photolysis of dibenzoyl peroxide" @default.
• W2070777744 cites W1985941517 @default.
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• W2070777744 doi "https://doi.org/10.1016/0009-2614(77)80220-0" @default.
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