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- W2070786722 abstract "The miscibilities of poly(vinyl chloride) (PVC) with poly(n-propyl acrylate), poly(n-butyl acrylate) and poly(n-pentyl acrylate) were studied. They were found to be miscible over the whole composition range at room temperature. Light-scattering turbidity, electron microscopy and glass-transition-temperature measurements showed them to phase-separate at higher temperatures. The phase diagrams of the various mixtures were determined. The polyacrylates with a higher concentration of carbonyl functional groups showed a higher phase-separation temperature. When the Flory equation-of-state theory was applied to the systems, a negative interaction entropy parameter Q12 had to be introduced to counterbalance the large negative interaction energy parameter X12, obtained from the heats of mixing of the oligomeric analogues, which resulted in the simulated spinodals being flat-bottomed. However, if a much smaller negative X12 was used, with a smaller Q12, the calculated spinodal had more curvature and corresponded closely to the measured phase-separation points." @default.
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- W2070786722 date "1987-04-01" @default.
- W2070786722 modified "2023-10-18" @default.
- W2070786722 title "Miscibility studies of poly(vinyl chloride) with polyacrylates: The thermodynamic and phase behaviour" @default.
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- W2070786722 doi "https://doi.org/10.1016/0032-3861(87)90232-1" @default.
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