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• W2070796344 abstract "The de novo asymmetric syntheses of several partially acylated dodecanyl tri- and tetra-rhamnoside natural products (cleistriosides-5 and 6 and cleistetrosides-2 to 7) have been achieved (19-24 steps). The divergent route requires the use of three or less protecting groups. The asymmetry was derived via Noyori reduction of an acylfuran. The rhamno-stereochemistry was installed by a diastereoselective palladium-catalyzed glycosylation, ketone reduction and dihydroxylation." @default.
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• W2070796344 date "2010-11-01" @default.
• W2070796344 modified "2023-10-12" @default.
• W2070796344 title "Synthesis of Several Cleistrioside and Cleistetroside Natural Products via a Divergent De Novo Asymmetric Approach" @default.
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• W2070796344 doi "https://doi.org/10.1021/ol1023344" @default.
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