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- W2070813201 abstract "UV-curable low surface energy fluorinated polycarbonate-based polyurethane dispersions were synthesized by incorporating a hydroxy-terminated perfluoropolyether (PFPE) into the soft segment of polyurethane. The effects of the PFPE content on the UV-curing behavior, physical, surface, thermal properties and refractive index were investigated. The UV-curing behavior was analyzed by photo-differential scanning calorimetry. The surface free energy of the UV-cured film, which is related to the water or oil repellency, was calculated from contact angle measurements using the Lewis acid-base three liquids method. The surface free energy decreased significantly with increasing fluorine concentration because PFPE in the soft segment was tailored to the surface and produced a UV-cured film with a hydrophobic fluorine enriched surface, as confirmed by X-ray photoelectron spectroscopy. With increasing the fluorine content, the refractive indices of UV-cured films decreased. However, the UV-curing rate and final conversion was decreased with increasing contents of PFPE, which resulted in the decrease of the glass transition temperature (T(g)), crosslink density, tensile strength and surface hardness." @default.
- W2070813201 created "2016-06-24" @default.
- W2070813201 creator A5008839214 @default.
- W2070813201 creator A5085980405 @default.
- W2070813201 date "2011-10-01" @default.
- W2070813201 modified "2023-10-08" @default.
- W2070813201 title "UV-curable low surface energy fluorinated polycarbonate-based polyurethane dispersion" @default.
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- W2070813201 doi "https://doi.org/10.1016/j.jcis.2011.06.044" @default.
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