FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2070831203> ?p ?o ?g. }

• W2070831203 endingPage "2785" @default.
• W2070831203 startingPage "2776" @default.
• W2070831203 abstract "Five new compounds, which bring together two classical groups, Werner transition-metal hexaammine complexes and sulfosalts, have been prepared from supercritical ammonia. They form in two different structure types which are built from traditional octahedrally coordinated transition-metal hexaammine cations and anionic networks that can be described as metalated derivatives of sulfosalts. The anionic framework of compound I, [Fe(NH3)6]Cu8Sb3S13, is built around a central Cu8S13 core in which copper atoms are surrounded by sulfur atoms in a very distorted tetrahedral coordination. These copper sulfide cores are linked together through bridging antimony atoms which assume a very regular tetrahedral coordination of sulfur atoms. The three mutually orthogonal channels created by the anion are filled with Fe(NH3)6 cations. In [Fe(NH3)6]AgES4 (E = Sb or As), II and III, respectively, the anionic framework is a one-dimensional chain built from alternating E− and Ag−sulfide tetrahedra that share opposite edges. In this structure type, hydrogen bonding apparently plays a role in the packing of the Fe(NH3)6 cations and anionic chains. Substitution of Fe with Mn or Ni in the synthesis results in compounds with the structure type observed in I. The synthetic routes and characterization, via X-ray crystallography, Mössbauer and IR spectroscopies, DSC, TGA, and bond valence sums are described. Crystal data: I, black cube, F4̄3c, a = 17.800(2) Å, V = 5640(1) Å3, Z = 8, R (wR) = 0.0432 (0.0472); II, yellow parallelepiped, P4̄n2, a = 10.274(2) Å, c = 6.707(2) Å, V = 707.9(3) Å3, Z = 2, R (wR) = 0.0249 (0.0297); III, yellow polyhedron, P4̄n2, a = 10.244(2) Å, c = 6.660(2) Å, V = 698.8(3) Å3, Z = 2, R (wR) = 0.0372(0.0423)." @default.
• W2070831203 created "2016-06-24" @default.
• W2070831203 creator A5006758709 @default.
• W2070831203 creator A5010740459 @default.
• W2070831203 creator A5019610701 @default.
• W2070831203 date "1997-12-01" @default.
• W2070831203 modified "2023-10-03" @default.
• W2070831203 title "Metal Hexaammine as a Bulky Cation: Structural and Property Studies of [M(NH₃)₆]Cu₈Sb₃S₁₃ (M = Mn, Fe, Ni) and [Fe(NH₃)₆]AgES₄ (E = As, Sb)" @default.
• W2070831203 cites W1622275449 @default.
• W2070831203 cites W1964727241 @default.
• W2070831203 cites W1968379858 @default.
• W2070831203 cites W1969683008 @default.
• W2070831203 cites W1974544013 @default.
• W2070831203 cites W1975299796 @default.
• W2070831203 cites W1976014436 @default.
• W2070831203 cites W1988145556 @default.
• W2070831203 cites W1999786403 @default.
• W2070831203 cites W2018483859 @default.
• W2070831203 cites W2028693862 @default.
• W2070831203 cites W2030354336 @default.
• W2070831203 cites W2036359892 @default.
• W2070831203 cites W2037023639 @default.
• W2070831203 cites W2044780503 @default.
• W2070831203 cites W2067219132 @default.
• W2070831203 cites W2074019256 @default.
• W2070831203 cites W2078312949 @default.
• W2070831203 cites W2090628660 @default.
• W2070831203 cites W2093409889 @default.
• W2070831203 cites W2094140808 @default.
• W2070831203 cites W2101748147 @default.
• W2070831203 cites W2126822973 @default.
• W2070831203 cites W2320075397 @default.
• W2070831203 cites W2949569259 @default.
• W2070831203 cites W2950954404 @default.
• W2070831203 cites W2951047363 @default.
• W2070831203 cites W2952390013 @default.
• W2070831203 cites W2952526921 @default.
• W2070831203 cites W2953004661 @default.
• W2070831203 doi "https://doi.org/10.1021/cm970095c" @default.
• W2070831203 hasPublicationYear "1997" @default.
• W2070831203 type Work @default.
• W2070831203 sameAs 2070831203 @default.
• W2070831203 citedByCount "53" @default.
• W2070831203 countsByYear W20708312032012 @default.
• W2070831203 countsByYear W20708312032013 @default.
• W2070831203 countsByYear W20708312032014 @default.
• W2070831203 countsByYear W20708312032015 @default.
• W2070831203 countsByYear W20708312032016 @default.
• W2070831203 countsByYear W20708312032017 @default.
• W2070831203 countsByYear W20708312032018 @default.
• W2070831203 countsByYear W20708312032019 @default.
• W2070831203 countsByYear W20708312032020 @default.
• W2070831203 countsByYear W20708312032021 @default.
• W2070831203 countsByYear W20708312032022 @default.
• W2070831203 crossrefType "journal-article" @default.
• W2070831203 hasAuthorship W2070831203A5006758709 @default.
• W2070831203 hasAuthorship W2070831203A5010740459 @default.
• W2070831203 hasAuthorship W2070831203A5019610701 @default.
• W2070831203 hasConcept C106773901 @default.
• W2070831203 hasConcept C115624301 @default.
• W2070831203 hasConcept C161790260 @default.
• W2070831203 hasConcept C168900304 @default.
• W2070831203 hasConcept C178790620 @default.
• W2070831203 hasConcept C179104552 @default.
• W2070831203 hasConcept C185592680 @default.
• W2070831203 hasConcept C2780596425 @default.
• W2070831203 hasConcept C544153396 @default.
• W2070831203 hasConcept C544778455 @default.
• W2070831203 hasConcept C55493867 @default.
• W2070831203 hasConcept C71240020 @default.
• W2070831203 hasConcept C8010536 @default.
• W2070831203 hasConceptScore W2070831203C106773901 @default.
• W2070831203 hasConceptScore W2070831203C115624301 @default.
• W2070831203 hasConceptScore W2070831203C161790260 @default.
• W2070831203 hasConceptScore W2070831203C168900304 @default.
• W2070831203 hasConceptScore W2070831203C178790620 @default.
• W2070831203 hasConceptScore W2070831203C179104552 @default.
• W2070831203 hasConceptScore W2070831203C185592680 @default.
• W2070831203 hasConceptScore W2070831203C2780596425 @default.
• W2070831203 hasConceptScore W2070831203C544153396 @default.
• W2070831203 hasConceptScore W2070831203C544778455 @default.
• W2070831203 hasConceptScore W2070831203C55493867 @default.
• W2070831203 hasConceptScore W2070831203C71240020 @default.
• W2070831203 hasConceptScore W2070831203C8010536 @default.
• W2070831203 hasIssue "12" @default.
• W2070831203 hasLocation W20708312031 @default.
• W2070831203 hasOpenAccess W2070831203 @default.
• W2070831203 hasPrimaryLocation W20708312031 @default.
• W2070831203 hasRelatedWork W1969124406 @default.
• W2070831203 hasRelatedWork W1999828662 @default.
• W2070831203 hasRelatedWork W2014969845 @default.
• W2070831203 hasRelatedWork W2028711677 @default.
• W2070831203 hasRelatedWork W2080922667 @default.
• W2070831203 hasRelatedWork W2081212010 @default.
• W2070831203 hasRelatedWork W2150940904 @default.
• W2070831203 hasRelatedWork W2314729056 @default.
• W2070831203 hasRelatedWork W2587246661 @default.
• W2070831203 hasRelatedWork W273092627 @default.

• next