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- W2070838145 abstract "Quaternary ammonium borohydrides, used directly or generated in phase transfer reactions, are highly effective reagents for preparing metal carbonyl anions from metal carbonyls [Mo(CO)6, Mn2(CO)10, Re2(CO)10, CO2(CO)8, Fe3(CO)12, Ru3(CO)12 and (η5-C5H5)2Mo2(CO)6] and from some metal carbonyl halides [BrMn(CO)5 and η5-C5H5Mo(CO)3Cl]. Where strongly basic anions would be formed from a halide [BrMn(CO)4PPh3 and η5-C5H5Ru(CO)2Br], the reactions provide efficient syntheses of the corresponding hydrides instead. The anion η5-C5H5Fe(CO)2− is not accessible by these techniques; reaction of η5-C5H5Fe(CO)2Br yields the iron dimer (via the highly nucleophilic anion) and the dimer is unreactive toward Q+BH4−. Reductions of Re2(CO)10 conducted in CH2Cl2 provide Re2(CO)9Cl− in high yield." @default.
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- W2070838145 date "1981-10-01" @default.
- W2070838145 modified "2023-09-23" @default.
- W2070838145 title "Reductions of metal carbonyls by quaternary ammonium borohydrides" @default.
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- W2070838145 doi "https://doi.org/10.1016/s0022-328x(00)81005-0" @default.
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