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- W2070867828 abstract "The simple HMO method extended to problems of ionic association of cations with organic radical anions by McClelland [1] and Goldberg and Bolton [2] was successfully used not only in the case of ion pair formation between nitrobenzene radical anion and univalent cations (eqn. (1)) but also when interactions are between this radical and water molecule (eqn. (2)). p]Inspection of a plot of log Kass against EHMOass for eqns. (1) and (2) leads to the conclusion that the treatment considered here, although very empirical, can be applied advantageously to prediction of association constants for equilibria like (1) and (2). The simplicity of this treatment suggests wide applications for more complex systems." @default.
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- W2070867828 date "1975-09-01" @default.
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- W2070867828 title "Quantum-chemical approach to the ion pair formation (IPF) equilibrium constants of nitrobenzene radical anions with univalent cations and water molecul" @default.
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- W2070867828 doi "https://doi.org/10.1016/0022-2860(75)80052-4" @default.
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