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• W2070883809 abstract "Coupling reactions of indoles forming 2,2'-biindolyls have been investigated. 2-Iodo-N-methyl-indole and unactivated copper gave N,N'-dimethyl-2,2'-biindolyl whereas activated copper yielded N-methyl-indole and the symmetrical trisindolobenzene 5. A mechanism involving the elimination of copper hydride to form a hetaryne intermediate is suggested. Coupling of N-benzenesulfonyl-2-lithioindole with CuCl2 yielded 2,2'-biindolyl after hydrolysis. N-methyl-2-lithioindole likewise gave N,N'-dimethyl-2,2'-biindolyl." @default.
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• W2070883809 date "1980-01-01" @default.
• W2070883809 modified "2023-10-09" @default.
• W2070883809 title "Synthesis of 2,2'-biindolyls by coupling reactions" @default.
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• W2070883809 doi "https://doi.org/10.1016/0040-4020(80)85059-9" @default.
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