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- W2070891851 endingPage "1771" @default.
- W2070891851 startingPage "1771" @default.
- W2070891851 abstract "The pincer ligand PPh(2-HSC6H4)2 reacts with GaCl3 in the presence of triethylamine to yield the anionic gallium complex [NEt3H][Ga{PPh(2-SC6H4)2-κ3S,S′,P}{PPh(2-SC6H4)2-κ2S,S′}] (1), which undergoes cation exchange with PPh4Cl to give [PPh4][Ga{PPh(2-SC6H4)2-κ3S,S′,P}{PPh(2-SC6H4)2-κ2S,S′}] (2). Neutral complexes GaR{PPh(2-SC6H4)2-κ3S,S′,P} [R = Me (3), tBu (4)] were obtained by reaction of PPh(2-HSC6H4)2 with trialkyl gallium compounds (GaMe3, GatBu3). Compound 4 is light-sensitive and decomposes in daylight or under UV irradiation. Three decomposition products could be isolated: tetranuclear hydrido-bridged mixed-valent gallium(II)–gallium(III) complex [GaIII{PPh(2-SC6H4)-κ2S,P-μ-(2-SC6H4)-κS′}2]2(μ3-H)2GaII2 (Ga–Ga) (5), gallium(II) complex [Ga{PPh(2-SC6H4)2-κ3S,S′,P}]2 (Ga–Ga) (6), and sulfido-bridged dinuclear complex [Ga{PPh(2-SC6H4)2-κ3S,S′,P}]2(μ-S) (7). The molecular structures of 2–7 are described." @default.
- W2070891851 created "2016-06-24" @default.
- W2070891851 creator A5007163105 @default.
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- W2070891851 date "2009-01-01" @default.
- W2070891851 modified "2023-10-18" @default.
- W2070891851 title "Stabilisation of an inorganic digallane by the phosphinobisthiolato P,S,S pincer ligand PPh(2-SC6H4)2" @default.
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- W2070891851 doi "https://doi.org/10.1039/b907668a" @default.
- W2070891851 hasPublicationYear "2009" @default.
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