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- W2070928415 abstract "The kinetics of polymerization of phenylacetylene in CDCl3 solution, intiated by Ph(MeO)CW(CO)5, has been followed under various conditions by in situ analysis of monomer (A) and initiator (F) using 1H n.m.r. spectroscopy. In degassed solution at 332 K the polymerization is zero order with respect to A and fractional order (0.7) with respect to F, the variation of rate with temperature (323–343 K) corresponding to an apparent activation energy of 116 kJ mol–1." @default.
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- W2070928415 date "1982-01-01" @default.
- W2070928415 modified "2023-10-10" @default.
- W2070928415 title "Kinetics and mechanism of polymerization of phenylacetylene initiated by (phenylmethoxycarbene)pentacarbonyltungsten(0)" @default.
- W2070928415 doi "https://doi.org/10.1039/f19827802227" @default.
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