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- W2070929393 abstract "Optically active C 3-symmetric monoanionic ligands are uncommon in organometallic chemistry. Here we describe the synthesis of readily prepared tris(4 S-isopropyl-2-oxazolinyl)phenylborate [To (P)] and fluxional, zwitterionic four- and five-coordinate iridium(I) compounds [Ir(To (P))(eta (4)-C 8H 12)] ( 4) and [Ir(To (P))(CO) 2] ( 5). The highly fluxional nature of 4 and 5 makes structural assignment difficult, and the interaction between the iridium(I) center and the [To (P)] ligand is established by solid-state and solution (15)N NMR methods that permit the direct comparison between solution and solid-state structures. Although iridium cyclooctadiene 4 is a mixture of four- and five-coordinate species, the dicarbonyl 5 is only the five-coordinate isomer. The addition of electrophiles MeOTf and MeI provides the oxazoline N-methylated product rather than the iridium methyl oxidative addition product. N-Methylation was unequivocally proven by through-bond coupling observed in (1)H- (15)N HMBC experiments." @default.
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- W2070929393 date "2008-11-17" @default.
- W2070929393 modified "2023-10-18" @default.
- W2070929393 title "Easily Prepared Chiral Scorpionates: Tris(2-oxazolinyl)boratoiridium(I) Compounds and Their Interactions with MeOTf" @default.
- W2070929393 doi "https://doi.org/10.1021/ic801637s" @default.
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