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- W2070938510 abstract "Abstract In order to provide standards for binding experiments of mutagenic arene imines to models of nucleic acids, we reacted N-methanesulfonyl phenanthrene 9,10-imine in DMSO in the presence of either potassium carbonate or 1,5-diazabicyclo[3.4.0]non-5-ene with several purine and pyrimidine bases. In these processes the aziridine ring cleaved and derivatives of 9,10-dihydro-9,10-phenanthrenediamine were formed. Cytosine, 5-fluorocytosine and thymine formed solely trans-N 1-adducts. Adenine and 6-chloropurine gave exclusively the corresponding N 9-products. Purine yielded a separable 2.2:1 mixture of trans-7-, and trans-9-[(9,10-dihydro-N-9-methane-sulfonamidophenanthren)-10-yl]purine. The structures of the adducts were determined by elemental analysis and by multi-nuclear and NOESY NMR spectrometry." @default.
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- W2070938510 date "1996-11-01" @default.
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- W2070938510 title "Adducts of a Polycyclic Arene Imine to Some Purines and Pyrimidines" @default.
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- W2070938510 doi "https://doi.org/10.1080/10406639608034695" @default.
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