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- W2070957568 abstract "Resolved isomers of O-n-hexyl-S-methylphosphorothioamidate (HXM) which had been synthesised by separate stereospecific routes were analysed by chiral glc: about 2-3% of R-(+) isomer was found in the S-(-) sample and accounted for nearly all the inhibitory power against neuropathy target esterase. Incubation of racemic HXM with rabbit serum led to slow but very specific disposal of R-(+) isomer to undetectable levels with very slight loss of S-(-): the rate of disposal was roughly estimated to be about 1% of the published rate of hydrolysis of paraoxon. Incubation with crystalline chymotrypsin caused a preferential but not totally selective disposal of S-(-) isomer." @default.
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- W2070957568 date "1993-06-01" @default.
- W2070957568 modified "2023-09-25" @default.
- W2070957568 title "Stereo-specific degradation of the R−(+) isomer of O-n-hexyl-S-methylphosphorothioamidate catalysed by rabbit serum" @default.
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- W2070957568 doi "https://doi.org/10.1016/0009-2797(93)90034-v" @default.
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