FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2070971520> ?p ?o ?g. }

• W2070971520 endingPage "294" @default.
• W2070971520 startingPage "292" @default.
• W2070971520 abstract "A practical stereoselective synthesis is reported for an alpha-trifluoromethyl-alpha-alkyl epoxide (1), which is an important pharmaceutical intermediate. The key step involves a chiral auxiliary-controlled asymmetric trifluoromethylation reaction for the introduction of the unique trifluoromethyl-substituted tertiary alcohol stereogenic center in the target molecule. The fluoride-initiated CF3 addition to chiral keto ester 6a proceeded with a diastereoselectivity up to 86:14. The major diastereomer was readily obtained with a >99.5:0.5 dr through a simple crystallization of the crude product mixture." @default.
• W2070971520 created "2016-06-24" @default.
• W2070971520 creator A5002126897 @default.
• W2070971520 creator A5011897505 @default.
• W2070971520 creator A5015397568 @default.
• W2070971520 creator A5040035765 @default.
• W2070971520 creator A5045387772 @default.
• W2070971520 creator A5050330206 @default.
• W2070971520 creator A5050500168 @default.
• W2070971520 creator A5051733915 @default.
• W2070971520 creator A5057948869 @default.
• W2070971520 creator A5058414000 @default.
• W2070971520 creator A5089826029 @default.
• W2070971520 creator A5090113453 @default.
• W2070971520 date "2006-12-09" @default.
• W2070971520 modified "2023-09-26" @default.
• W2070971520 title "Practical Stereoselective Synthesis of an α-Trifluoromethyl-α-alkyl Epoxide via a Diastereoselective Trifluoromethylation Reaction" @default.
• W2070971520 cites W1979006910 @default.
• W2070971520 cites W2016731880 @default.
• W2070971520 cites W2035382144 @default.
• W2070971520 cites W2050970476 @default.
• W2070971520 cites W2057431263 @default.
• W2070971520 cites W2086885624 @default.
• W2070971520 cites W2112992162 @default.
• W2070971520 cites W2135785239 @default.
• W2070971520 cites W2949815083 @default.
• W2070971520 cites W2950197149 @default.
• W2070971520 cites W2950807284 @default.
• W2070971520 cites W2951452242 @default.
• W2070971520 cites W2951787378 @default.
• W2070971520 cites W2952739980 @default.
• W2070971520 doi "https://doi.org/10.1021/jo061839l" @default.
• W2070971520 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17194115" @default.
• W2070971520 hasPublicationYear "2006" @default.
• W2070971520 type Work @default.
• W2070971520 sameAs 2070971520 @default.
• W2070971520 citedByCount "34" @default.
• W2070971520 countsByYear W20709715202012 @default.
• W2070971520 countsByYear W20709715202013 @default.
• W2070971520 countsByYear W20709715202014 @default.
• W2070971520 countsByYear W20709715202015 @default.
• W2070971520 countsByYear W20709715202016 @default.
• W2070971520 countsByYear W20709715202017 @default.
• W2070971520 countsByYear W20709715202019 @default.
• W2070971520 countsByYear W20709715202022 @default.
• W2070971520 countsByYear W20709715202023 @default.
• W2070971520 crossrefType "journal-article" @default.
• W2070971520 hasAuthorship W2070971520A5002126897 @default.
• W2070971520 hasAuthorship W2070971520A5011897505 @default.
• W2070971520 hasAuthorship W2070971520A5015397568 @default.
• W2070971520 hasAuthorship W2070971520A5040035765 @default.
• W2070971520 hasAuthorship W2070971520A5045387772 @default.
• W2070971520 hasAuthorship W2070971520A5050330206 @default.
• W2070971520 hasAuthorship W2070971520A5050500168 @default.
• W2070971520 hasAuthorship W2070971520A5051733915 @default.
• W2070971520 hasAuthorship W2070971520A5057948869 @default.
• W2070971520 hasAuthorship W2070971520A5058414000 @default.
• W2070971520 hasAuthorship W2070971520A5089826029 @default.
• W2070971520 hasAuthorship W2070971520A5090113453 @default.
• W2070971520 hasConcept C134195300 @default.
• W2070971520 hasConcept C138716334 @default.
• W2070971520 hasConcept C144000664 @default.
• W2070971520 hasConcept C146686406 @default.
• W2070971520 hasConcept C161790260 @default.
• W2070971520 hasConcept C178790620 @default.
• W2070971520 hasConcept C181647583 @default.
• W2070971520 hasConcept C185592680 @default.
• W2070971520 hasConcept C2776442012 @default.
• W2070971520 hasConcept C2776920199 @default.
• W2070971520 hasConcept C2779061078 @default.
• W2070971520 hasConcept C2780263894 @default.
• W2070971520 hasConcept C2781066024 @default.
• W2070971520 hasConcept C71240020 @default.
• W2070971520 hasConceptScore W2070971520C134195300 @default.
• W2070971520 hasConceptScore W2070971520C138716334 @default.
• W2070971520 hasConceptScore W2070971520C144000664 @default.
• W2070971520 hasConceptScore W2070971520C146686406 @default.
• W2070971520 hasConceptScore W2070971520C161790260 @default.
• W2070971520 hasConceptScore W2070971520C178790620 @default.
• W2070971520 hasConceptScore W2070971520C181647583 @default.
• W2070971520 hasConceptScore W2070971520C185592680 @default.
• W2070971520 hasConceptScore W2070971520C2776442012 @default.
• W2070971520 hasConceptScore W2070971520C2776920199 @default.
• W2070971520 hasConceptScore W2070971520C2779061078 @default.
• W2070971520 hasConceptScore W2070971520C2780263894 @default.
• W2070971520 hasConceptScore W2070971520C2781066024 @default.
• W2070971520 hasConceptScore W2070971520C71240020 @default.
• W2070971520 hasIssue "1" @default.
• W2070971520 hasLocation W20709715201 @default.
• W2070971520 hasLocation W20709715202 @default.
• W2070971520 hasOpenAccess W2070971520 @default.
• W2070971520 hasPrimaryLocation W20709715201 @default.
• W2070971520 hasRelatedWork W2070971520 @default.
• W2070971520 hasRelatedWork W2084535056 @default.
• W2070971520 hasRelatedWork W2085228319 @default.
• W2070971520 hasRelatedWork W2091000527 @default.
• W2070971520 hasRelatedWork W2321931537 @default.
• W2070971520 hasRelatedWork W2901079269 @default.

• next