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- W2070978107 abstract "In this paper we apply the Aptekar-Ponyatovsky (AP) regular solution thermodynamic model to the analysis of experimental data for the coefficient of thermal expansion (CTE) and determine the AP model parameters for unalloyed cerium metal, Ce-Th-La alloys, and Pu-Ga alloys. We find that the high temperature CTE of cerium metal follows the predictions of the AP model based on low temperature, high pressure data. For Ce-Th-La alloys we use the AP parameters to track the suppression of the first-order γ-α cerium transition. We show the AP model accounts for the negative CTE observed for Pu-Ga alloys and is equivalent to an earlier invar model. Finally, we apply the AP parameters obtained for Pu-Ga alloys to rationalize the observed δ-α transformation pressures of these alloys. We show that the anomalous values of the Grüneisen and Grüneisen-Anderson parameters are important features of the thermal properties of plutonium. A strong analogy between the properties of plutonium and cerium is confirmed." @default.
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- W2070978107 date "2011-08-22" @default.
- W2070978107 modified "2023-10-17" @default.
- W2070978107 title "Thermal expansion and transformation behavior of cerium and plutonium alloys: an application of the Aptekar–Ponyatovsky regular solution model" @default.
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- W2070978107 doi "https://doi.org/10.1088/0953-8984/23/36/365803" @default.
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